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Ozone Resistance

Testing Elastomers for Environmental Influences

Under normal environmental ozone concentrations elastomer materials may form deep cracks which usually lead to a failure of a component. But the following conditions are prerequisite:

  • a highly unsaturated polymer, e.g. NBR, NR or SBR
  • a deformation > 3-5%
  • an admission of ozoniferous air (an unbraked air exchange at the seal)

In practice this occurs particularly at pre-installed NBR-seals which are exposed to their environment. In contrast this does normally not occur at installed seals. To a certain degree NBR-materials can be protected against the exposure of ozone by certain additives. The effectiveness of these additives can be ascertained by ozone tests. In the process samples are exposed to a defined ozone concentration (e.g. 50 pphm) at a given stretching (e.g. 20%) over a limited period of time (e.g. 48h). Afterwards the sample is checked for cracks.

The Richter O-ring testing laboratory currently has 3 ozone testing devices available to carry out ozone resistance tests on behalf of customers.

Standards: DIN 53 509, ISO 1431.

Further services:

Hardness and density are fast and easily ascertained. Therefore, they are ideal for incoming goods inspection and testing.

The hardness test is probably the most applied and most common test method in the elastomer industry.

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Ozone cracks

Although the damaging effect of ozone on many elastomers has been known for over 150 years, it still causes seal failure. Ozone cracking always occurs perpendicular to the direction of stress.